Product ID:1306,WORKABLE FIXATIF,43803
MSDS Date:08/20/1994
FSC:8010
NIIN:Submitter:D DG
Status Code:A
MSDS Number: CJZTL

SHERWIN-WILLIAMS CO, SPECIALTY PRODUCTS DIV.

31500 SOLON ROAD
SOLON, OH 44139-5000
US

Emergency Phone: 800-777-2966

Info Phone: 800-777-2966

Preparer: NOT PROVIDED.

Cage: DO642

SHERWIN-WILLIAMS CO THE SPECIALTY DIV.

6709 SOLON, OH 44139-3908 US

Telephone: 216-292-7400

Cage: DO642

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9495

BUTYL BENZYL PHTHALATE (SARA 313) (CERCLA)

CAS: 85-68-7

RTECS: TH9990000

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE

CAS: 108-65-6

RTECS: AI8295000

OSHA PEL NOT ESTABLISHED.

ACGIH TLV: NOT ESTABLISHED.

ACETONE (SARA 313) (CERCLA)

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 1000 PPM

ACGIH TLV: 750PPM/1000STEL;9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOPROPYL ALCOHOL (SARA 313)

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM/500STEL;9495

ISOBUTANE

CAS: 75-28-5

RTECS: TZ4300000

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9495

VOLATILE ORGANIC CONTENT = 94 WT %

RTECS: 9999999VO

Fraction By Weight: 94%

LD50 LC50 Mixture:NOT PROVIDED.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE HEALTH HAZARDS EFFECTS OF
OVEREXPOSURE: IRRITATION OF EYES, SKIN, RESPIRATORY SYSTEM. MAY
CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY CAUSE
UNCONSCIOUSNESS AND POSSIBLY DEATH. CHR ONIC HEALTH HAZARDS:
PROLONGED OVEREXPOSURE TO SOLVENT MAY CAUSE ADVERSE EFFECTS TO THE
LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR AND REPRODUCTIVE
SYSTEMS. REPORT HAVE ASSOCIATED REPEATED AND PROL ONGED
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE.
Explanation of Carcinogenicity:NO INGREDIENT IN THESE PRODUCTS IA AN
IARC, NTP OR OSHA LISTED CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, LOSS OF
COORDINATION ARE INDICATIONS OF OVEREXPOSUSRE TO VAPORS OR MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR
EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:IF INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE -USE. IF IN EYES: FLUSH EYES WITH LARGE AMOUNT OF
WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: GET
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<-17.6C, 0.F
FLAMMABL AEROSOL
Lower Limits:0.9
Upper Limits:12.8
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY
BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE.
WATER MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT AND IGNITION SOURCES.
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. EXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAU SE A HEALTH HAZARD. SYMPTOMS MAY
NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION.

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE
AND REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NOT RELEVANT.

Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP
AWAY FROM HEAT, SPARKS, OPEN FLAME. VAPORS WILL ACCUMULATE READILY
AND MAY IGNITE EXPLOSIVELY. CONTENTS UNDER PRESSURE. DO NOT
PUNCTURE, INCINERATE/EXPOSE TO TEM PERATURE ABOVE 120F. DURING USE
AND UNTIL ALL VAPORS ARE GONE, KEEP AREA VENTILATED. DO NOT SMOKE.
Other Precautions:DO NOT TAKE INTERNALLY. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL
OR FATAL. HEAT FROM SUNLIGHT, RADIATORS, STOVE, HOT WATER COULD
CAUSE CONTAINER TO BUR ST. KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION
AGAINST LISTED INGREDI ENTS.
Ventilation:USE LOCAL EXHAUST PEREFERABLE. GENERAL EXHAUST IS
ACCEPTABLE IF THE EXPOSURE TO INGREDIENTS IS MAINTAINED BELOW
APPLICABLE EXPOSURE LIMITS.
Protective Gloves:NONE REQUIRED FOR NORMAL OPERATIONS. CHEMICAL
RESISTANT FOR REPEATED CONTACT.
Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Other Protective Equipment:FOR PROLONGED AND/OR REPEATED CONTACT WEAR
CHEMICAL RESISTANT GLOVES.
Work Hygienic Practices:USE ONLY WITH ADEQUATE VENTILATION. AVOID
BREATHING VAPORS AND MISTS. AVOID DIRECT OR PROLONGED CONTACT WITH
SKIN AND EYES. WASH HANDS AFTER USING.
Supplemental Safety and Health
NONE

HCC:V3
NRC/State Lic Num:NOT RELEVANT.
Boiling Pt:B.P. Text:<0F - 195F
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT PROVIDED.
Vapor Pres:NOT GIVEN
Vapor Density:>1
Volatile Org Content %:94
Spec Gravity:NOT AVAILABLE.
pH:NOT RELEVANT.
Viscosity:NOT PROVIDED.
Evaporation Rate & Reference:FASTER THAN ETHER
Solubility in Water:NOT AVAILABLE.
Appearance and Odor:MFR GAVE NO INFORMATION ON MSDS.
Percent Volatiles by Volume:NOT PROVIDED
Corrosion Rate:NOT PROVIDED.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NOT PROVIDED.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE,CARBON MONOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:WASTE FROM THESE PRODUCTS MAY BE HAZARDOUS AS
DEFINED UNDER THE RCRA (40CFR261). WASTE MUST BE TESTED FOR
IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE
NUMBERS. DO NOT INCINERATE. DEPRE SSURIZE CONTAINER. DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLL
UTION.

Toxicological Information:NOT PROVIDED.

Ecological:NOT PROVIDED.

Transport Information:NOT PROVIDED.

SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
(SARA) OF 1986 AND 40 CFR PART 372.65C: ACETONE 60%, BUTYL BENZYL
PHTHALATE 1%, 2-BUTOXYETHANOL 2%.
Federal Regulatory Information:NOT PROVIDED.
State Regulatory Information:CALIFORNIA PROPOSITION 65: SOME OF THESE
PRODUCTS CONTAIN A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.